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| • Down the Group, first ionization energy (the energy required to remove 1 electron from the gaseous atom) decreases. As the atomic radius increases and the electron is further from the nucleus it is less attracted to the nucleus (electron is said to be 'shielded') |
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| Ionization energies decrease as atomic radii increase. This observation is affected by \(n\) (the principal quantum number) and \(Z_{eff}\) (based on the atomic number and shows how many protons are seen in the atom) on the ionization energy (I). The relationship is given by the following equation: |
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| The adaptation of Neil Gaiman’s and Terry Pratchett’s Good Omens has just filled out several more of its cast. The series has found three of four Horsemen of the Apocalypse as well as the ultimate demon Beelzebub for the Amazon and BBC Two series. Anna Maxwell Martin ( Becoming Jane) will star as Beelzebub while Mireille Enos ( The Killing) will play War, Lourdes Faberes ( Knightfall) as Pollution and Yusuf Gatewood ( The Originals) as Famine. On Martin’s casting, Gaiman said “We already have a stellar cast, and now Anna Maxwell Martin will be the Beelzebub of our dreams. Well, nightmares.” “A script this clever, this smart, this current is very rare,” said Enos. “How could I turn down playing one of the Horsemen of the Apocalypse??? Especially with the incredible group who’s come together to make it. It’s going to be Fun!” “It’s a gift for |
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| A naturally occurring stand-alone and intermolecular Diels–Alderase, MaDA, has been identified from Morus alba cell cultures. MaDA is a FAD-dependent enzyme, which catalyses the intermolecular [4+2] cycloaddition via a concerted but asynchronous pericyclic pathway between morachalcone A and a diene generated from moracin C. Characterization revealed that MaDA possesses good substrate promiscuity towards both dienes and dienophiles. |
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